Electronic structures of two different azido complexes of the 5,7,7,12,14,14-hexamethyl-I,4,8,11-TE TRAA zacyclote trade canenichel(II) ion, 1977
Ngai, Raymond
1970-1979
The electronic structures of the complex dimer, 5.7.7.12.14.14-hexamethyl-l,4,8,11-tetraazacyclotetra-decanenickel(II)-y-diazido-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecanenickel(II) ion, ([(Ni(tet-b)N3)2]^+), and the diazido complex, diazido-5.7.7.12.14.14-hexamethyl-l,4,8,11-tetraazacyclotetrade-canenickel (II), ( [Ni( tet-a) (Ng^] ), have been studied. Spectroscopic and crystal field data of the two azido complexes are presented. Energies of the d-d transition and charge transfer bands were also determined. An attempt to show the generation of nitrene intermediate by the photolysis of [(Ni(tet-b)N3)2]^+ ion was unsuccessful.
text
application/pdf
1977-12-01
thesis
Master of Science (MS)
Atlanta University
Department of Chemistry
Reed, James L.
Clark Atlanta University
Georgia--Atlanta
http://hdl.handle.net/20.500.12322/cau.td:1977_ngai_raymond