Date of Award
Department of Chemistry
James L. Reed
The electronic structures of the complex dimer, 220.127.116.11.14.14-hexamethyl-l,4,8,11-tetraazacyclotetra-decanenickel(II)-y-diazido-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecanenickel(II) ion, ([(Ni(tet-b)N3)2]^+), and the diazido complex, diazido-18.104.22.168.14.14-hexamethyl-l,4,8,11-tetraazacyclotetrade-canenickel (II), ( [Ni( tet-a) (Ng^] ), have been studied. Spectroscopic and crystal field data of the two azido complexes are presented. Energies of the d-d transition and charge transfer bands were also determined. An attempt to show the generation of nitrene intermediate by the photolysis of [(Ni(tet-b)N3)2]^+ ion was unsuccessful.
Ngai, Raymond, "Electronic structures of two different azido complexes of the 5,7,7,12,14,14-hexamethyl-I,4,8,11-TE TRAA zacyclote trade canenichel(II) ion" (1977). ETD Collection for AUC Robert W. Woodruff Library. 3816.